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In episode 5, DeWitt wears two very different outfits.
The first is a bright, canary-yellow sweater with elbow-length sleeves and a cross-over neckline border, worn over a tweed pencil skirt. The pencil skirt is not a new look for DeWitt, but the colour of the sweater is much brighter than the usual muted tones she favours.
You don't want to make her angry.
Here's a good view of the sleeve length:
The second is her go-to black pencil skirt with a very interesting forest-green blouse, made in a silky, drapey fabric. It has a slightly cowled neckline and a fascinating construction for the sleeves: the material overlaps from the shoulder seam to the wrist.
From the back: